>> Needless to say VC was a bit unstable when playing around with Tkinter
in PythonScript behaviours but i'm sure that's no news to anyone.
Its the simple fact that the python interpretter does not run the way a normal python does, it runs in special stackless mode. So you would need to write the code in a bit uinituitive manner. Which unfortunately is not documented in most python tutorials or examples. This simple fact makes avenues of normal operation unworking because the gui frameworks tend rely on threads. And a stackless python has no thereads so to speak.
So all avenues relying on thereds implicitly or excplicitly will fail, This leads to the feeling its unstable, because they will simply not work normally. This said the 2010 release is running on python 2.5 which should make life a bit easeier in this regard. This is also the reason why I dont feel comfortable writing examples ate the moment because i should test them 2 times over. But since the new system is not up and running I must postpone such things till next week. Also there might be a much easier way to make dialogs, but that is only if it works well enough.
But i was intending on testing operation fo Qt in 2010 on my own time.
>> Is it possible to write an 'Add-on' application that runs on 3D Realize 2007 using COM?
No, and its not really intended for this kind of use unfortunately.